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The Biofuel Papers

This entry is intended to serve as an index to the three papers I’ve written on the topic of biofuels, and in particular how to derive a payback period for a biofuel crop. Such a consideration inevitably suggests that growing biofuels on a given plot of land is a bad idea. It’s just a question of how long there’s going to more global warming for if you grow biofuels than if you don’t – centuries in many cases.

A few months ago I outlined the argument in a systematic step-by-step manner in Biofuel Payback Periods (pdf) (5 sides plus footnotes).

My somewhat longer initial essay treatment a year ago, Biofuels Are Not the Answer (pdf) (6 sides plus footnotes), takes a slightly broader view.

I also last year produced a slightly more elaborate critique of the idea that biofuels displace fossil fuel use – The Displacement Fallacy (pdf) (just 1 side).

PS (26/6/08): Updated Biofuels Are Not the Answer after noticing some broken links in the footnotes. Version 1.1.1, rather than version 1.1, is now referenced.

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Sternly bemused at Realclimate

I was over at Realclimate yesterday, researching something entirely different – but related, obviously – when I can across a post referring to the discounting conundrum. I’m afraid to say I couldn’t resist making a contribution and then another one.

I have to say that the more I think about the issue of GW cost discounting, the more I harden my position. It seems to me that valuing the future less than the present has all the characteristics of a self-fulfilling prediction. We should not discount future capital losses compared to present expenditure.

My parting shot over at Realclimate included the ever so slightly controversial claim that:

“…[the cost of GW] damage will increase with GDP, since economic damage caused by GW will be proportionate to the total GDP whenever it occurs (e.g. consider that Stern discusses insurance losses in terms of total global GDP). [Equivalent funds] I invest will also increase with GDP…”

I fully expected this statement to be attacked, so had to have a riposte ready before posting. [Postscript (a few minutes after writing this post): I was wondering if the lack of activity on the Realclimate thread was because the Moderator had had a Bank Holiday lie-in. It now seems this may well have been the case. There’s now more to read over there].

I was worried that people would claim they could obtain a long-term investment return exceeding GDP. No they can’t. The so-called risk-free rate applies to government bonds. If I could achieve a return greater than the growth in GDP, that would imply that by investing in government bonds and reinvesting the return – in effect doing nothing, by definition, since this is the risk-free rate of return we are talking about – I could, over time, grow my wealth as a share of GDP. That would be nonsense. Merv and Gordo are stupid, but not that stupid.

But I now see (thanks to a presentation [pdf] by Mike Hanemann referred to in a Realclimate post) that it is the other side of the equation – my assertion that the cost of damage will increase with GDP – that is where Stern’s discount rate comes from. The Hanemann presentation notes that:

“Factors underlying the interest rate
• Pure rate of social time preference (ρ)
• How much richer the future generation will be (g)
• If they are richer, how much that lowers the value of money to them (η)
• Interest rate is: r = ρ + ηg
– Nordhaus & Stern both use same η (=1) and similar g (= 1.3%)
– Nordhaus uses ρ = 2.3-3%; Stern ρ = 0.1%
– Result is that for Stern r = 1.4%, while for Nordhaus r = 3.6 – 4.3%. “

[If you’re slightly confused that John Broome in Sci Am claims “Nordhaus discounts at roughly 6 percent a year”, then we’re in the same boat].

Nordhaus’ ρ = 2.3-3% is a self-fulling prediction as I’ve already pointed out. We can hardly avoid future catastrophe by, in effect, simply saying it doesn’t matter much.

My basic problem is with the idea that future generations will be “richer”. What does this actually mean? However rich we are, GW has the potential to destroy fixed proportions of our capital. If Cambridge ever disappears into the North Sea, we will lose a proportion of all the capital ever invested in Cambridge whether this happens in 2008, 2058, 2108 or 2808. Residents in New Orleans lost their houses whether these had all mod cons or hadn’t been modified for 50 years. They lost their TVs whether they were 1960s B&W sets or the latest wide-screen hi-def plasmas. Similarly many people in the Irrawaddy delta have lost everything, regardless of how rich they were. We may all have smart ecohomes in 2108, but we won’t necessarily have the capacity to replace them more quickly (actually our capacity to replace housing stock in the UK is slower than it was 50 years ago). The cost of a catastrophic flood in the East of England will be x thousand houses (and y hectares of farmland lost to the sea etc) whatever their nominal value or indeed how much real costs in terms of time and non-salvageable materials have been invested in them.

The idea that we are 1.3% “richer” each year is a bizarre economic construction. We may just have more sophisticated assets to lose in the future, that’s all.

If the whole planet is rendered uninhabitable by GW, it won’t matter how “rich” we are. Similarly if 10% or 1% is lost or degraded (e.g. due to sea-level rise or desertification) this is 10% or 1%, however rich we are.

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Still Sternly Bemused

Following my previous post, I’m still mulling over the topic of whether we should “Pay Now or Pay More Later” for the costs of climate change. I feel a need to extract the bear bones of the argument questioning whether discount rates apply at all to the “costs” of global warming. The previous post muddies the waters a little by bringing in additional (though valid) arguments, such as that it may be necessary to distinguish between consumption and capital formation.

It still seems to me that the principle of internalisation of costs – which I thought was established in the mainstream as the way to deal with the global warming problem – and the idea that the polluter pays – which again I thought was not seriously doubted as the appropriate principle – lead to a need to consider carbon emissions made now as a debt owed by the emitter to the global population, not as a cost that might be incurred in the future which doesn’t matter much because we’ll all be rich.

If we do this, then it follows that we have to be temporally impartial. If I have a debt of the form that a cost will be occurred (global warming related losses in this case) at some unknown point in the future, then I can amortise the cost of that debt over time – i.e. pay interest – or, if I’m sensible, insure myself – but not reduce it simply because the risk has not yet materialised. To assume otherwise is to be like the Lloyds of London Names who were wiped out when they were hit with insurance losses due to asbestosis. Note also that the businesses the Names kindly insured may have made a profit for their shareholders, but only because the shareholders avoided paying the costs in damage to health that came to light later. The asbestos businesses are analogous to today’s carbon emitters.

It also follows from the debt idea that we must be utilitarian and not prioritarian. (This is quite apart from the fact that there is no justification for the assumption that we will all be richer in the future). Consider buying a PC. By (say) 1995, it was quite clear that we all had a choice between buying a PC for (say) $1000 or putting the $1000 in the bank and buying a much, much better PC for (say) $1400 ($1000 + compounded interest) in 2000. We all struggled with this choice. It generated a million letters to PC magazines asking “Should I buy now or wait?”. The point is that we didn’t say to ourselves: “I won’t forgo a PC now because in the future I’ll be able to afford PC’s easily”. This argument is analogous to that of the prioritarians. It has zero logic. Sorry, negative logic. I can only afford more computers in the future if I don’t spend all my money on computers now, not if I do! Duh!

The problem is that, in dreaming up their daft arguments for “prioritarianism” and “temporal partiality”, the economists have failed to think about how we attribute the costs of carbon emissions, either to mankind as a whole (and I’ve resisted the temptation in pointing out that the cost of species and ecosystem loss is not only infinite – extinction is forever – but that rich people, as we will supposedly all be in the future, put a higher relative value on the environment than do poor people, an argument that could actually make the discount rate negative), individual nations (which is particularly dumb, as the global community is going to hold the historical polluters to their share of the costs one way or another) or individuals. We don’t have to actually answer the question (not easy – it’s going to lead to a lot of argument over the coming decades!), but, as soon as we ask ourselves: “Who’s going to pay for the damage caused by these emissions?” it becomes obvious that the discount rate should be zero. Anyone who argues that we can simply reduce the debt by 1.4% a year or 6% a year or whatever daft figure they dream up is simply spouting tosh.

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Sternly bemused

Ever since the Stern Review report came out last year I’ve been baffled by the debate on discount rates. Something bothers me, but until now I haven’t been able to put my finger on it.

Effect on GDP of catastrophic events due to global warming

My gut feel is that the costs of catastrophic events have somehow been underestimated.

What I’m worried about in particular is the effect on cities (aka concentrations of fixed capital) of rising sea levels exacerbated by storms (though the loss of other resources – farmland, roads etc – is of course important too, and could cumulatively be even more significant). Some time ago my finger in the air estimate was that the loss of capital due to the forced evacuation of a great city – Shanghai was the one I came up with – would be around $1trn a pop, at today’s prices. My point is: how could the global economy keep growing if such losses become a regular occurrence?

Looking back at the Stern Report I see that there is a section on this very point – section 5.4 Impacts of extreme events (p.149ff in my CUP print copy). “Costs of extreme weather alone could reach 0.5 – 1% of GDP”, it says – currently they are 0.2% or $60bn p.a. on average. In 2005 the loss was $200bn, largely due to Katrina. Stern also notes that “Miami alone has $900bn worth of total capital stock at risk.” (p.150). On the other hand “developed economies… invest a considerable amount in fixed capital each year (20% of GDP or $5.5trn…)” of which $1.5trn goes into construction. Now I am able to quantify my qualms. Bear with me here: I freely admit I’m in a bit of a qualm quantification quandary!

1. GDP includes both consumption and capital formation. Now, it is the capital formation that allows us to grow GDP. To put it simply, it is all the new factories we build this year that allow us to consume more next year. If we stop forming capital (i.e. net investment goes to zero), then GDP growth will also fall to zero. We can’t (say) provide more transport without building more transport infrastructure, factories to produce vehicles etc.

2. Now, Stern notes that capital formation is around 20% of GDP in developed countries. I see no reason to suppose that this type of GDP (aka economic activity) can displace consumption. What I mean is, the resources that support consumption (private cars, say) cannot be diverted into the production of fixed capital (car factories, say) – at least not easily. To put it another way, if buildings are destroyed in a storm flood, they can either be rebuilt or other buildings can be built elsewhere (as intended before the catastrophic event) – you can’t do both unless you have spare construction resources.

3. So, I suggest, long-term GDP growth depends on the growth rate of capital formation.

4. It follows that average annual losses of fixed capital of Stern’s 0.5% – 1% of GDP will reduce the rate of fixed capital formation – which is only 20% of GDP – by 100%/20% times the proportional GDP loss, that is by 2.5% – 5%.

5. So GDP growth will in the long-run be 2.5% – 5% less than otherwise, not the 0.5% – 1% range Stern refers to.

6. Compound this effect on growth and GDP, even at the lower end (an average reduction in capital formation of 2.5% p.a.), if we allow global warming to happen, will only be around 75% of what it would be otherwise after a mere decade and less than a third after 40 years – so anyone starting out on their working life now will have a retirement living standard 1/3 of what it would otherwise have been. If we allow global warming to happen, that is.

7. Sanity check: refugees from a city rendered uninhabitable will move somewhere else and either:

  • be poor (reducing total GDP that way), or,
  • if fully insured, push up the price of housing etc, in effect lowering everyone’s standard of living, and again reducing total GDP.

8. I guess ultimately the economy might respond and allocate more resources to construction and other fixed capital formation. But if the losses are scattered moreorless randomly through time and around the world, it may be very inefficient to permanently maintain a larger pool of construction resources (how will the market do this?). One year they’d be needed, another not, the next they’d be needed on the other side of the world. Furthermore, for such a change in resource allocation to have no effect on overall GDP growth rates would imply that capital formation is not at present proceeding at an optimal rate. If it is possible to permanently increase the rate of capital formation without other repercussions for the economy – and note that high rates of capital formation tend to be associated with the accumulation of environmental debt, which is what’s getting us in this mess in the first place! – then there would nevertheless certainly be a permanent reduction in consumption as a percentage of GDP.

Hmm…

Response to “The Ethics of Climate Change”

In the last couple of days, an article, “The Ethics of Climate Change” by John Broome in Scientific American (June 2008 ) has led me to take a somewhat different tack and suggest that economists are making a category error when they model the reduction of carbon emissions as a cost that can, if necessary, be deferred. It is surely not a case of the “sacrifices the present generation will have to make to reduce greenhouse gases” (as John Broome puts it in Scientific American) but one of the environmental debt that will continue to be run up as long as we fail to internalise the costs of our emissions.

It is the science that tells us that the elevated level of greenhouse gases is an example of an environmental debt. For example, because the annual amount of carbon dioxide the ocean can absorb has levelled off (according to the IPCC, and as discussed previously in Uncharted Territory) then, at the margin, an extra tonne of carbon dioxide emitted now by the burning of fossil fuels or land-use change will remain in the atmosphere indefinitely. Each year the extra tonne of atmospheric carbon will cause the Earth to gain more heat than it would have done otherwise, causing environmental or financial damage (or at least increasing the risk of such damage in any given year).

Carbon dioxide emissions effectively incur an (until now unaccounted) interest charge payable in perpetuity in terms of environmental damage. It may make sense to establish an international trade in cuts in emissions compared to notional business as usual levels, so that emission reductions are made most efficiently (or at least more politically expediently than would otherwise be the case), but, when we are trying to determine the optimal global emissions reduction path, it is (IMHO) a mistake to consider emission cuts as a form of expenditure. Overall emission reduction targets must rather be motivated by a consideration of the cost of increasing our collective environmental debt that would otherwise be incurred.

And this isn’t the same thing at all. No, no, no!

The problem cannot be analysed as if it were that of an individual deferring costs over their lifetime, on the grounds (say) that they’ll have more money when their career takes off. To put it bluntly, (and think about the analogy of an individual’s lifetime spending profile) deferring forgoing consumption is simply not postponing a cost (as Stern et al would have us believe) – it’s consuming now and taking on debt. And as we – the post credit crunch generation – know only too well, debts can get out of hand. Am I starting to make sense?

Consider further that the existing international consensus is to implicitly attribute the global warming debt to individual nation states on the basis of their “historical emissions” through consumption of fossil fuels. (One might argue that fossil fuel producer countries and those that have caused carbon emissions through land‑use change have also incurred a debt). Instead of philosophising we can simply look at how international debt is managed today. Government debt is rarely written off – that of developed countries almost never. It follows that we should be temporally impartial (see the Scientific American article for an explanation) in assessing when to make emission reductions. In other words, it would be very imprudent to apply a discount rate on the basis that the cost of damage caused by today’s emissions will be less in the future. This is why it’s so important that we don’t treat a debt as a cost. If I borrow a dollar today I have to pay back more than a dollar in the future. But if I spend a dollar today that is worth more than to me than if I spend a dollar in future.

The question remains as to whether we should be prioritarian (again, see the Scientific American article). To determine this we must look at the present balance sheet of Earth Enterprises inc., taking into account the net present value of the environmental debt. Taking on the environmental debt results in at least some capital investment. The interest on the environmental debt represents future destruction of capital. How should this destruction be discounted in deciding the optimal path of future carbon emissions? The loss of a city in 50 years time due to rising sea levels and more intense storms will cause the loss of today’s capital represented by the city as well as the investment made over the next 50 years. However many bathrooms there are in each house (the article suggests that we can discount because we’ll have more bathrooms in the future), they’ll all be destroyed. The same proportion of global capital will be lost by the destruction of the city in 50 years as would be lost if it were destroyed tomorrow. As for the temporal consideration, we must simply use present-day costs – a discount rate of zero.

As pointed out in the Stern Review, the cost of – or rather, the environmental debt incurred as a result of – greenhouse gas emissions depends on their level in the atmosphere at the time. That is, because of the limited ability of natural systems to absorb increased emissions and eventual positive carbon cycle feedbacks, the marginal cost of a tonne of carbon emissions increases (in real terms) as atmospheric greenhouse gas levels and the temperature increase. This conclusion suggests two possible international conversations:

  • First, responsibility for historical emissions can be quantified if politicians wish to attempt such an exercise, but at a lower cost to present emissions.
  • Second, the cost of future emissions will be higher than even present-day emissions. My bank manager would have little sympathy if I asked him to grant me a cheap mortgage simply because I missed the opportunity to borrow before the credit crisis, when money was cheap. Similarly, the fact that carbon emissions were cheap in the past is not a valid argument against them being made very expensive for everybody now.

Conclusion

The conventional economic approach – as espoused by Stern and characterised by a discourse focussing on the “costs” of global warming and, as a consequence, making use of discount rates – is deeply suspect.

An alternative approach which is more in tune with the international consensus perception of global warming (and other environmental externality problems) is to characterise the elevation of levels of greenhouse gases as an environmental debt, attributable to nation states or as may otherwise be politically determined.

Such an approach immediately exposes the fallacy of temporal discounting – international debts are typically never forgiven, or, if they are, this is seen as akin to an act of charity. We must be temporally impartial in assessing the costs of global warming (and other environmental debts).

Neither can we be prioritarian and plead present-day poverty. The debt-based approach also reveals that capital losses cannot be simply equated with the loss of consumption opportunities. The error is akin to a company trying to convince the investment community that a loss of $100m in a financial year is tiny compared to its turnover of $5bn. It is only relevant to compare the scale of the loss with the company’s capital. Additionally, losses of capital will be proportionate to the total capital at the time of the loss – any more optimistic assumption would be reckless.

The correct approach therefore is to use a discount rate of zero for global warming losses, and account for all global warming debts at present-day prices. That is, if the emission of a tonne of carbon now increases the risk of the 50% loss of the fixed capital investment represented by a given city in 50 years time by 0.000001%, then the cost of (=the debt incurred by emitting) that carbon is 0.000001% of 50% of the value of the city now, not 0.000001% of 50% of the value of the city discounted by a factor of the order of some percent raised to the power 50 (i.e. multiplied by for example 98.6% – Stern’s figure – or 94% – Nordhaus’ estimate for each of 50 years – try this one at home to see the effect!). To put it bluntly, if Miami has to be permanently evacuated and 50% of the cumulative fixed capital investment in the city ($900bn at present-day prices) is lost, then it is 50% whether the event happens tomorrow, in 50 years time or in 150 years time. Whenever it happens we still have to build New Miami. If you happen to be responsible for some of the environmental debt that causes this to happen, I hope you’ve invested the carbon wisely!

In translating the risk of future losses – that is, the total environmental debt due to greenhouse gas emissions – into a price of carbon we must also take into account that the warming effect of a tonne of emissions at a given time depends on the total amount of emissions up to that point in time. As in any financial market, the cost of a commodity (in this case the right to emit) depends on the behaviour of all other participants in the market.

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Ocean CO2 uptake update

The IPCC AR4 Scientific Basis report is a real goldmine of information, even if it isn’t perfect, as I recently pointed out.

As I discussed in a previous post, an idea I later developed a little, policies to address global warming must rely on an understanding of how natural systems will respond to the increase in atmospheric CO2. Will the oceans keep absorbing a couple of GtC worth of CO2 each year (as estimated since 1990 – AR4, p.26, as referenced previously) or more (as implicitly assumed by many) or less? And will land ecosystems manage to take up more or less carbon than in the past? Especially if we continue to reduce the area of ecosystems able to do this – since agricultural land clearly does not progressively store carbon.

I’ve been looking at a critical section in AR4 on ocean uptake of CO2. This is 5.4.2.2 on p.403-5 (though the main section on the carbon cycle is 7.3, p.511 ff). I quote:

“The fraction of net CO2 emissions taken up by the ocean (…) was possibly lower during 1980 to 2005 (37% +/- 7% [that is, 118 +/- 19 of 283 +/- 19GtC of emissions]) compared to 1750 to 1994 (42% +/- 7% [that is, 53 +/- 9 of 143 +/- 10 GtC of emissions)… The decrease in oceanic uptake fraction would be consistent with the understanding that the ocean CO2 sink is limited by the transport rate of anthropogenic carbon from the surface to the deep ocean, and also with the nonlinearity in carbon chemistry that reduces the CO2 uptake capacity of water as its CO2 concentration increases”. (my inserts in [ ]’s – based on Table 5.1, p.404).

And we also have to worry about “a decrease in CO2 uptake capacity” as the ocean warms.

On the other hand section 7.3.2.2.5 (p.521) notes that:

“The ocean uptake has increased by 22% between the 1980s and 1990s, but the fraction of emssions (fossil plus land use) taken up by the ocean has remained constant.”

though of course the ocean “knows” nothing about emissions – all it can possibly be affected by is the level of CO2 in the atmosphere.

We really need to get a handle on what the oceans are going to do in the future since it makes such a huge difference to the level of carbon emissions we can get away with. It’ll be the first section I turn to in AR5. As AR5 is due around 2012 (I suppose), maybe we should have a think about where we focus scientific resources now…

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Some thoughts on sorts of science sources

OK, it’s not quite up there in the tongue-twister stakes as my best creation: “We’re wearing weird red wellies”. Try saying that quickly after a few pints!

About 10 days ago my Sunday morning was spoilt by the sight of the really rather scary, formerly reassuringly plump (maybe he’s become a vegan) ex-Chancellor of the UK Exchequer Nigel Lawson on Andrew Marr’s weekly political couch-fest. Why had he crawled out of his coffin? Well, to plug his book, of course. It is indeed one of the world’s great mysteries why the BBC is so careful not to mention products by name (to utter “Coca-Cola” without permission would be blasphemous in Beebland), yet so shamelessly allows so many people to promote their products. The occasion of Ryanair’s financial results, for example, seem to provide a free 1 minute advertising slot for Michael O’Leary. I’m surprised he doesn’t move to quarterly reporting.

Presumably, if you have good PR help, a public profile or the right connections, you can get as much time to plug a book on the BBC as you want, because, blow me down if I didn’t hear Count Lawson again on the radio a few days ago, on some type of pick of the week show on Radio 4. At least he was being grilled this time – listen and learn, Andrew Marr. But surely there should be some criteria for whether a book is worthy of BBC airtime? E.g. positive reviews by experts in the field?? Tricky, but how could anything be worse than the apparent old school tie basis of selection we have today?

Get this, Lawson’s book was turned down, he said on TV, by 7 UK publishers, but he has a “good agent” who managed to get it published overseas. Makes you wonder if it’s really worthy of promotion in the mainstream media, don’t it? I was therefore going to put TV bottom of the list of reliable science sources.

But then I read the Times’ review of Nigel Lawson’s contribution to the debate. Astonishingly, the reviewer, an Alexander Cockburn, chides Lawson for accepting the anthropogenesis of global warming! In fact, Cockburn’s review leaves me with the impression that Lawson may be saying something useful. A view dispelled by a somewhat more comprehensive (family connections?) review in the Spectator. Lawson, it seems (before I rush out to buy his work), doesn’t deny global warming, he merely downplays it, in order to argue against doing anything much at all (I’ll be more specific when I’ve read the book – which I will likely do, because, unfortunately, publicity grants de facto credibility, requiring a response). Insidious.

So, let’s award 0/10 for the informativeness of the mainstream print media (Times) and 1/10 for the broadcasters (BBC), who at least attempt to be impartial. Let’s give general current affairs (Spectator) 2/10. And let’s give published works 3/10. At least the publishers tried to stop Lawson, if to no avail; perhaps his memory of the Spycatcher affair stood him in good stead.

Now, compare this piece by Gwyn Prins from the Guardian’s Commentisfree site. For all I know, Gwyn Prins makes similar points about the ineffectiveness and counterproductivity of existing policy responses to GW as does Nigel Lawson, but at least he does not base his argument on false premises. In fact, I was interested enough to download Prins’ paper “The Wrong Trousers: Radically Rethinking Climate Policy” (written jointly with Steve Rayner). Prins & Rayner argue that GW is serious and urgent, but the Kyoto mechanism ineffective. They therefore advocate “enlightened self-interest” (ouch!). Still, a step forward from the “downplaying” strategy of a failed UK Chancellor (the Lawson Boom was followed by an inflationary bust – anyone else notice a pattern starting to develop? – let’s ignore problems until it’s too late, shall we, Nigel?).

So, let’s say 4/10 for op-ed (as the Yanks call it), and 5/10 for online publications.

But what I want to draw attention to are the exchanges in the comments on Prins’ piece. First, let’s backtrack a little. Lawson (like Nigel Calder) apparently claims the Earth is no longer warming, since annual average global temperatures have not returned to their 1998 record level. Now, as we all know, temperatures are bound to fluctuate from year to year about a long-term warming trend. All the scatter of annual mean temperatures tells us is that the annual variability of transfer of heat from the surface of the oceans exceeds the amount of heat gained by the planet each year. But, if the oceans were to cease gaining heat, without an overt cooling cause (such as a volcano) then GW theory would be in trouble – it would imply (since the oceans are so large and important in this context) that the Earth is no longer cooler than it needs to be for it to be in energy balance. Unfortunately, this is exactly what the IPCC’s 4AR implies. Yes, Fig. 5.1 on page 390 shows the oceans cooling over the last few years. Does the IPCC really explain this anomaly? No. It is “bottom-up” science – based more on observation than theory-driven.

So, say 8/10 to the IPCC. Maybe they need to put a bit more effort into the coherence of the whole package, and resolve or at least discuss these sorts of problems before rushing their 900 pages to CUP.

Anyway, I was mulling over this problemette when I noticed it discussed by PacificGatePost and deconvoluter in the comments on Prins’ Guardian piece. Phew! It turns out there was a problem with the measurements. deconvoluter refers to a Realclimate piece that gives chapter and verse.

So let’s give blogs (Commentisfree) 6/10 and specialist blogs (Realclimate) 9/10. Now we’re getting somewhere.

But there’s more. The Prins piece was in response to an article in Nature, by Roger Pielke et al arguing that the IPCC scenarios (actually I consider these unrealistic and irrelevant, but let’s put that to one side for now) are over-optimistic. The scenarios – shock!, horror! – assume some carbon “savings” will occur without specific policy to reduce emissions (um, anyone seen the price of oil today?). Now, even though the Pielke article and a Nature editorial are accessible on the internet, much of their content is subscriber only, so it does rather perturb me that so much debate (rather than actual science) is being conducted (in Scienglish) in the pages of Science and Nature. Not their fault, but what are the mainstream media doing? I believe as many people as possible need to develop their own understanding of the science and the issues. “Trust me, I’m a scientist” is only going to get us so far.

So, 7/10 in our informativeness competition to science magazines.

I gave the Realclimate site 9/10 – for trying to bridge the gap between the scientific world and normal people – but they’re not the real winner. 10/10, and the top prize goes to – yes, you’ve guessed it! – the internet itself which has made all this possible. Without it, I suggest the GW debate would be years behind even where it is now.

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Confused by carbonates

Somebody please help!

I’m having great difficulty reconciling two things that I’ve read:

1. There is a carbonate “saturation horizon” at a specific depth in the oceans. Below this depth carbonates dissolve because of the high pressure. (The “saturation horizon” depth is also less where it is colder).

What’s going on is that there is a chemical equilibrium:

Ca2+ + HCO3 <–> CaCO3 + H+

Adding CO2 to the oceans – a result of adding it to the atmosphere – makes the problem worse. It acidifies the water, driving this equilibrium to the left, in effect dissolving carbonates, such as the shells of marine organisms. (The big danger is that this process will raise the carbonate saturate horizon to the surface in the polar oceans, leading to a sudden increase in acidity in the absence of the carbonate buffer, which will reduce the ability of the ocean to absorb carbon dioxide, as well as prevent organisms from making carbonate exoskeletons).

2. There is a plan afoot to dump carbon dioxide underground, in gas and oil fields and in saline aquifers (”carbon capture and sequestration” or CCS). There was an interesting article on this by Fred Pearce in last week’s New Scientist (subscriber’s only, I’m afraid). Now, said Fred, “… the chemical reactions might gradually convert the CO2 into carbonate rock…”. But Fred also mentions the Frio project when the CO2 “…acidified the brine allowing it to dissolve metal-oxide minerals in the rock…” which “…might eventually create tunnels in the cap rock through which CO2 might escape”.

My question is, why wouldn’t the CO2 in general form an acid (I assume there’s plenty of water about) and dissolve the rock? In particular, how could it form carbonate rock, when, as we see in the oceans, CO2 in solution forms an acid which dissolves carbonate rock – more effectively at pressure? Surely this could only happen once all the CO2 had been converted to some intermediate form? – since otherwise any remaining CO2 would form acid and dissolve the carbonate. Can we therefore always rely on the sequestered CO2 staying where it’s put?

Of course, I’ve consulted “Sustainable Fossil Fuels” by Mark Jaccard who notes that: “… the CO2 may eventually either dissolve into the aquifer water (hydrodynamic trapping) or precipitate as a solid carbonate mineral by reacting with the surrounding rock (mineral trapping).” OK…

When I look at the IPCC Special Report on CCS, I see they go into all this in more detail, of course. I guess I’m happy with the chemistry – on its own – and I’m happy with the mechanics – permeability, cap-rocks etc. – on its own. It’s the interaction between the chemistry and the physics of the rock formations that bothers me. The IPCC notes that:

“Reaction of the dissolved CO2 with minerals can be rapid (days) in the case of some carbonate minerals…” (section 5.2.2.3, p.209).

and that:

“Reaction of the CO2 with formation water and rocks may result in reaction products that affect the porosity of the rock and the flow of solution through the pores. This possibility has not, however, been observed experimentally and its possible effects cannot be quantified.” (section 5.2.2, p.210).

Perhaps we’d better quantify it before we get our hopes for CCS up too high. What was the Frio project if it wasn’t an experiment? Puzzlingly, the IPCC report only mentions the Frio project as 1600tCO2 “pilot” (Table 5.1, p.201) and one of several that:

“…demonstrate that subsurface injection of CO2 is not for the distant future, but is being implemented now for environmental and/or commercial reasons.” (section 5.1.2, p.204).

What is this? A scientific evaluation or a sales brochure?

In general, is the approach being adopted to evaluating CCS one of identifying all the problems so that we can avoid them when we roll-out the technology, or one of trying to show that there are no problems, so that we can carry on planning to burn fossil-fuels (and building coal-fired power-stations) with as few qualms as possible?

One other annoying fact: liquid CO2 is less dense than water, so if there is enough pressure and the reservoir is not sealed, it’s the CO2 that will leak out, not the H2O.

Any comments that might help allay my fears are more than welcome.

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Implications of ‘peak oil’ – Tim’s Translation Service

No sooner had I digested the Target Atmospheric CO2 paper than another one (pdf) arrived, courtesy of James Hansen’s mailing list.

The paper “Implications of ‘peak oil’ for atmospheric CO2 and climate”, Pushker A. Kharecha and James E. Hansen (pdf) makes a similar argument to that in “Target Atmospheric CO2″, though there are some differences.

I’ll try to keep the translation brief this time.

Summary

The paper seeks to show that we can keep CO2 below 450ppm [Hansen argued for less in “Target Atmospheric CO2″] by avoiding burning coal to the atmosphere, and using a high price of CO2 to deter the use of unconventional (e.g. tar sand) and other expensive sources of oil. Various Peak Oil scenarios imply that we can keep below 450ppm CO2, based on the Bern carbon cycle model, with both a static pulse response function (PRF) and a dynamic PRF. That is, even if some carbon cycle feedbacks are allowed for, CO2 can be kept below 450ppm if we burn all the existing conventional oil and natural gas reserves.

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